Interactions of organic additives with calcite crystals of different morphologies
Principal investigator
Precipitated calcium carbonate (PCC) is a synthetic mineral product, which has found
application in various industrial fields, mainly as filler and/or pigment. However, the
application of PCC is strongly dependent on its morphology and the size distribution. The
control and design of a desired crystal morphology and crystal size can be achieved by
applying specific additives during crystal growth process. The process is actually controlled
by selective interaction of additives with distinct surface sites. The objective of the proposed
visit is to study the interactions of organic additives, particularly phosphonates and
carboxylates, with calcite crystals of different morphologies. Different experimental
approaches will be applied: sorption/precipitation growth kinetics analyses and surface
sensitive analytics, under the supervision of highly skilled scientist at Karlsruhe Institute of
Technology and Schaefer-Kalk. This visit would allow main applicant to learn about new
crystal growth techniques, such as mixed-flow reactor, to acquire the knowledge on
molecular processes at calcite/aqueous solution interfaces as well as to learn about the
precipitation of calcium carbonate at industrial scale. The main applicant will transfer this
knowledge to Ruđer Bošković Institute and the proposed visit would be the initial step for the
collaboration between the scientists from the institutions involved.